Here's my initial attempt for the induction:
We start with n = 1 case:
$< \partial f, \phi (x)> = <-f, \partial\phi (x)> $ for the general function $\phi(x)$. We can integrate by parts to get from LHS to get to RHS. This also holds for $\phi(x) = \delta(x)$. Then, for the n = 2 case, we can redefine a new function:
$<\partial^2 f, \phi(x)> = <-F, \partial^2\phi(x)>$ for the general function $\phi(x)$. We could also just redefine the functions in such a manner that we get the expression:
$<\partial F, \phi(x)> = <-f,\partial \phi(x)>$, it also holds for $\delta(x)$
Then generalizing to order n = k, we can show it holds. Where F is the primitive for f. We can always reduce it to just a first order derivation instead of kth order.